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Quaternary β(2,2)-amino acid derivatives by asymmetric addition of isoxazolidin-5-ones to para-quinone methides†

The highly enantioselective (>99.5% ee) synthesis of a new class of densely functionalized β(2,2)-amino acid derivatives by reacting isoxazolidin-5-ones with para-quinone methides in the presence of chiral ammonium salt phase-transfer catalysts was developed. The reaction proceeds with exceptiona...

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Bibliografische gegevens
Gepubliceerd in:Chem Commun (Camb)
Hoofdauteurs: Eitzinger, Andreas, Winter, Michael, Schörgenhumer, Johannes, Waser, Mario
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2020
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7082149/
https://ncbi.nlm.nih.gov/pubmed/31830176
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9cc09239k
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