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Enolization rates control mono- versus di-fluorination of 1,3-dicarbonyl derivatives
Fluorine-containing 1,3-dicarbonyl derivatives are essential building blocks for drug discovery and manufacture. To understand the factors that determine selectivity between mono- and di-fluorination of 1,3-dicarbonyl systems, we have performed kinetic studies of keto–enol tautomerism and fluorinati...
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| Veröffentlicht in: | Chem Sci |
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| Hauptverfasser: | , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Royal Society of Chemistry
2019
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6979503/ https://ncbi.nlm.nih.gov/pubmed/32110319 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc04185k |
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