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Engineered C–N Lyase: Enantioselective Synthesis of Chiral Synthons for Artificial Dipeptide Sweeteners

Aspartic acid derivatives with branched N‐alkyl or N‐arylalkyl substituents are valuable precursors to artificial dipeptide sweeteners such as neotame and advantame. The development of a biocatalyst to synthesize these compounds in a single asymmetric step is an as yet unmet challenge. Reported here...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Zhang, Jielin, Grandi, Eleonora, Fu, Haigen, Saravanan, Thangavelu, Bothof, Laura, Tepper, Pieter G., Thunnissen, Andy‐Mark W. H., Poelarends, Gerrit J.
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2019
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Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6973171/
https://ncbi.nlm.nih.gov/pubmed/31625664
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201910704
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