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A Photoactivatable Small‐Molecule Probe for the In Vivo Capture of Polyketide Intermediates
A photolabile carba(dethia) malonyl N‐acetylcysteamine derivative was devised and prepared for the trapping of biosynthetic polyketide intermediates following light activation. From the lasalocid A polyketide assembly in a mutant strain of the soil bacterium Streptomyces lasaliensis, a previously un...
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| Veröffentlicht in: | Chemistry |
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| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
John Wiley and Sons Inc.
2019
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6972646/ https://ncbi.nlm.nih.gov/pubmed/31617624 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201903661 |
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