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Regioselective Hydrosilylation of Olefins Catalyzed by a Molecular Calcium Hydride Cation
Chemo‐ and regioselectivity are often difficult to control during olefin hydrosilylation catalyzed by d‐ and f‐block metal complexes. The cationic hydride of calcium [CaH](+) stabilized by an NNNN macrocycle was found to catalyze the regioselective hydrosilylation of aliphatic olefins to give anti‐M...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
John Wiley and Sons Inc.
2019
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6972613/ https://ncbi.nlm.nih.gov/pubmed/31609062 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201909585 |
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