Acyl Migration versus Epoxidation in Gold Catalysis: Facile, Switchable, and Atom‐Economic Synthesis of Acylindoles and Quinoline Derivatives

We report a switchable synthesis of acylindoles and quinoline derivatives via gold‐catalyzed annulations of anthranils and ynamides. α‐Imino gold carbenes, generated in situ from anthranils and an N,O‐coordinated gold(III) catalyst, undergo electrophilic attack to the aryl π‐bond, followed by unexpe...

ver descrição completa

Na minha lista:
Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Tian, Xianhai, Song, Lina, Farshadfar, Kaveh, Rudolph, Matthias, Rominger, Frank, Oeser, Thomas, Ariafard, Alireza, Hashmi, A. Stephen K.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Research Articles
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6972584/
https://ncbi.nlm.nih.gov/pubmed/31622542
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201912334
Tags: Adicionar Tag
Sem tags, seja o primeiro a adicionar uma tag!

Registos relacionados