Acyl Migration versus Epoxidation in Gold Catalysis: Facile, Switchable, and Atom‐Economic Synthesis of Acylindoles and Quinoline Derivatives

We report a switchable synthesis of acylindoles and quinoline derivatives via gold‐catalyzed annulations of anthranils and ynamides. α‐Imino gold carbenes, generated in situ from anthranils and an N,O‐coordinated gold(III) catalyst, undergo electrophilic attack to the aryl π‐bond, followed by unexpe...

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Dettagli Bibliografici
Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Tian, Xianhai, Song, Lina, Farshadfar, Kaveh, Rudolph, Matthias, Rominger, Frank, Oeser, Thomas, Ariafard, Alireza, Hashmi, A. Stephen K.
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2019
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Research Articles
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6972584/
https://ncbi.nlm.nih.gov/pubmed/31622542
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201912334
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