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Iron‐Mediated Electrophilic Amination of Organozinc Halides using Organic Azides
A wide range of alkyl‐, aryl‐ and heteroarylzinc halides were aminated with highly functionalized alkyl, aryl, and heterocyclic azides. The reaction proceeds smoothly at 50 °C within 1 h in the presence of FeCl(3) (0.5 equiv) to furnish the corresponding secondary amines in good yields. This method...
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| Опубликовано в: : | Angew Chem Int Ed Engl |
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| Главные авторы: | , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
John Wiley and Sons Inc.
2019
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6972526/ https://ncbi.nlm.nih.gov/pubmed/31599056 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201911704 |
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