Terminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms

Despite their importance as mechanistic models for heterogeneous Haber Bosch ammonia synthesis from dinitrogen and dihydrogen, homogeneous molecular terminal metal-nitrides are notoriously unreactive towards dihydrogen, and only a few electron-rich, low-coordinate variants demonstrate any hydrogenol...

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Publicat a:Nat Commun
Autors principals: Chatelain, Lucile, Louyriac, Elisa, Douair, Iskander, Lu, Erli, Tuna, Floriana, Wooles, Ashley J., Gardner, Benedict M., Maron, Laurent, Liddle, Stephen T.
Format: Artigo
Idioma:Inglês
Publicat: Nature Publishing Group UK 2020
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Article
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6969212/
https://ncbi.nlm.nih.gov/pubmed/31953390
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-14221-y
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