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Halogenated triphenylgallium and -indium in frustrated Lewis pair activations and hydrogenation catalysis
The Lewis acids Ga(C(6)F(5))(3), In(C(6)F(5))(3) and Ga(C(6)Cl(5))(3) are prepared and their Lewis acidity has been probed experimentally and computationally. The species Ga(C(6)F(5))(3) and In(C(6)F(5))(3) in conjunction with phosphine donors are shown to heterolytically split H(2) and catalyse the...
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| Publicado no: | Philos Trans A Math Phys Eng Sci |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The Royal Society Publishing
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5540843/ https://ncbi.nlm.nih.gov/pubmed/28739969 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1098/rsta.2017.0014 |
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