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Nitrous oxide as a primary product in base-mediated β-elimination reactions of diazeniumdiolated benzylamine derivatives

We report an unexpected β-elimination pathway by which diazeniumdiolated benzylamines of structure Bn–N(R)–N(O)= N–OR(′) undergo base-mediated fragmentation to generate N(2)O as the only gaseous product. The reaction is especially rapid for R = 2-hydroxyethyl, in which the hydroxyl group anchimerica...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Chem Commun (Camb)
Prif Awduron: Biswas, Debanjan, Cao, Zhao, Keefer, Larry K., Saavedra, Joseph E.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2012
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC6959517/
https://ncbi.nlm.nih.gov/pubmed/22572739
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c2cc32284f
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