Enzyme-catalysed [6+4] cycloadditions in the biosynthesis of natural products

Pericyclic reactions are powerful transformations for the construction of carbon–carbon and carbon–heteroatom bonds in organic synthesis. Their role in biosynthesis is increasingly apparent, and mechanisms by which pericyclases can catalyse reactions are of major interest(1). [4+2] cycloadditions (D...

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Detalhes bibliográficos
Publicado no:Nature
Main Authors: Zhang, Bo, Wang, Kai Biao, Wang, Wen, Wang, Xin, Liu, Fang, Zhu, Jiapeng, Shi, Jing, Li, Ling Yu, Han, Hao, Xu, Kuang, Qiao, Hong Yun, Zhang, Xiao, Jiao, Rui Hua, Houk, Kendall N., Liang, Yong, tan, Ren Xiang, Ge, Hui Ming
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6944468/
https://ncbi.nlm.nih.gov/pubmed/30867595
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41586-019-1021-x
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