Enzyme-catalysed [6+4] cycloadditions in the biosynthesis of natural products

Pericyclic reactions are powerful transformations for the construction of carbon–carbon and carbon–heteroatom bonds in organic synthesis. Their role in biosynthesis is increasingly apparent, and mechanisms by which pericyclases can catalyse reactions are of major interest(1). [4+2] cycloadditions (D...

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Veröffentlicht in:Nature
Hauptverfasser: Zhang, Bo, Wang, Kai Biao, Wang, Wen, Wang, Xin, Liu, Fang, Zhu, Jiapeng, Shi, Jing, Li, Ling Yu, Han, Hao, Xu, Kuang, Qiao, Hong Yun, Zhang, Xiao, Jiao, Rui Hua, Houk, Kendall N., Liang, Yong, tan, Ren Xiang, Ge, Hui Ming
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2019
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6944468/
https://ncbi.nlm.nih.gov/pubmed/30867595
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41586-019-1021-x
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