Enzymatic Intermolecular Hetero-Diels–Alder Reaction in the Biosynthesis of Tropolonic Sesquiterpenes

Diels–Alder reactions are among the most powerful synthetic transformations to construct complex natural products. Despite that increasing of enzymatic intramolecular Diels–Alder reactions have been discovered, natural intermolecular Diels–Alderases are rarely described. Here, we report an intermole...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Chen, Qibin, Gao, Jie, Jamieson, Cooper, Liu, Jiawang, Ohashi, Masao, Bai, Jian, Yan, Daojian, Liu, Bingyu, Che, Yongsheng, Wang, Yanan, Houk, K. N., Hu, Youcai
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6944466/
https://ncbi.nlm.nih.gov/pubmed/31461283
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b06592
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