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Accelerating the Shuttling in Hydrogen-Bonded Rotaxanes: Active Role of the Axle and the End Station

[Image: see text] The relation between the chemical structure and the mechanical behavior of molecular machines is of paramount importance for a rational design of superior nanomachines. Here, we report on a mechanistic study of a nanometer scale translational movement in two bistable rotaxanes. Bot...

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Détails bibliographiques
Publié dans:J Am Chem Soc
Auteurs principaux: Kumpulainen, Tatu, Panman, Matthijs R., Bakker, Bert H., Hilbers, Michiel, Woutersen, Sander, Brouwer, Albert M.
Format: Artigo
Langue:Inglês
Publié: American Chemical Society 2019
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6923795/
https://ncbi.nlm.nih.gov/pubmed/31697078
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b10005
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