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Influence of axle length on the rate and mechanism of shuttling in rigid H-shaped [2]rotaxanes
A series of [2]rotaxane molecular shuttles was prepared containing a dibenzo[24]crown-8 (DB24C8) wheel and a rigid H-shaped axle with varying track lengths between recognition sites; from 7.4 to 20.3 Å as defined by 1–4 phenyl rings or a naphthyl group. The rate of shuttling was measured by variable...
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| Foilsithe in: | Chem Sci |
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| Main Authors: | , , , , , |
| Formáid: | Artigo |
| Teanga: | Inglês |
| Foilsithe: |
Royal Society of Chemistry
2017
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| Ábhair: | |
| Rochtain Ar Líne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5851341/ https://ncbi.nlm.nih.gov/pubmed/29568435 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc03736h |
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