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The lubricating role of water in the shuttling of rotaxanes

We have investigated at the atomic level amide-based rotaxanes set in motion in four different solvents, namely, ethyl ether, acetonitrile, ethanol and water. In three non-aqueous solvents, shuttling of the macrocycle between two binding sites separated by a free-energy barrier is coupled with a con...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Chem Sci
Prif Awduron: Fu, Haohao, Shao, Xueguang, Chipot, Christophe, Cai, Wensheng
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: Royal Society of Chemistry 2017
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC5613241/
https://ncbi.nlm.nih.gov/pubmed/28970894
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc01593c
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