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Spacer Length‐Independent Shuttling of the Pillar[5]arene Ring in Neutral [2]Rotaxanes

For a series of neutral [2]rotaxanes consisting of a pillar[5]arene ring and axles possessing two stations separated by flexible spacers of different lengths, the free energies of activation for the ring shuttling between the stations were found to be independent of the spacer length. The constituti...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Ogoshi, Tomoki, Kotera, Daisuke, Nishida, Shungo, Kakuta, Takahiro, Yamagishi, Tada‐aki, Brouwer, Albert M.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5947626/
https://ncbi.nlm.nih.gov/pubmed/29473232
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201800104
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