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Spacer Length‐Independent Shuttling of the Pillar[5]arene Ring in Neutral [2]Rotaxanes

For a series of neutral [2]rotaxanes consisting of a pillar[5]arene ring and axles possessing two stations separated by flexible spacers of different lengths, the free energies of activation for the ring shuttling between the stations were found to be independent of the spacer length. The constituti...

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Опубликовано в: :Chemistry
Главные авторы: Ogoshi, Tomoki, Kotera, Daisuke, Nishida, Shungo, Kakuta, Takahiro, Yamagishi, Tada‐aki, Brouwer, Albert M.
Формат: Artigo
Язык:Inglês
Опубликовано: John Wiley and Sons Inc. 2018
Предметы:
Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC5947626/
https://ncbi.nlm.nih.gov/pubmed/29473232
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201800104
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