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Deciphering the enzymatic mechanism of sugar ring contraction in UDP-apiose biosynthesis

D-Apiose is a C-branched pentose sugar important for plant cell wall development. Its biosynthesis as UDP-D-apiose involves decarboxylation of the UDP-D-glucuronic acid precursor coupled to pyranosyl-to-furanosyl sugar ring contraction. This unusual multistep reaction is catalyzed within a single ac...

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Detalhes bibliográficos
Publicado no:Nat Catal
Main Authors: Savino, Simone, Borg, Annika J. E., Dennig, Alexander, Pfeiffer, Martin, de Giorgi, Francesca, Weber, Hansjörg, Dubey, Kshatresh Dutta, Rovira, Carme, Mattevi, Andrea, Nidetzky, Bernd
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6914363/
https://ncbi.nlm.nih.gov/pubmed/31844840
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41929-019-0382-8
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