Structural Mimics of Acetylene Hydratase: Tungsten Complexes Capable of Intramolecular Nucleophilic Attack on Acetylene

Bioinspired complexes employing the ligands 6‐tert‐butylpyridazine‐3‐thione (SPn) and pyridine‐2‐thione (SPy) were synthesized and fully characterized to mimic the tungstoenzyme acetylene hydratase (AH). The complexes [W(CO)(C(2)H(2))(CHCH‐SPy)(SPy)] (4) and [W(CO)(C(2)H(2))(CHCH‐SPn)(SPn)] (5) were...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Vidovič, Carina, Peschel, Lydia M., Buchsteiner, Michael, Belaj, Ferdinand, Mösch‐Zanetti, Nadia C.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6899645/
https://ncbi.nlm.nih.gov/pubmed/31603595
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201903264
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