Structural Mimics of Acetylene Hydratase: Tungsten Complexes Capable of Intramolecular Nucleophilic Attack on Acetylene

Bioinspired complexes employing the ligands 6‐tert‐butylpyridazine‐3‐thione (SPn) and pyridine‐2‐thione (SPy) were synthesized and fully characterized to mimic the tungstoenzyme acetylene hydratase (AH). The complexes [W(CO)(C(2)H(2))(CHCH‐SPy)(SPy)] (4) and [W(CO)(C(2)H(2))(CHCH‐SPn)(SPn)] (5) were...

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Bibliographic Details
Published in:	Chemistry
Main Authors:	Vidovič, Carina, Peschel, Lydia M., Buchsteiner, Michael, Belaj, Ferdinand, Mösch‐Zanetti, Nadia C.
Format:	Artigo
Language:	Inglês
Published:	John Wiley and Sons Inc. 2019
Subjects:	Communications
Online Access:	https://ncbi.nlm.nih.gov/pmc/articles/PMC6899645/ https://ncbi.nlm.nih.gov/pubmed/31603595 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201903264
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Structural Mimics of Acetylene Hydratase: Tungsten Complexes Capable of Intramolecular Nucleophilic Attack on Acetylene

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