Bioinspired Nucleophilic Attack on a Tungsten-Bound Acetylene: Formation of Cationic Carbyne and Alkenyl Complexes

[Image: see text] Inspired by the proposed inner-sphere mechanism of the tungstoenzyme acetylene hydratase, we have designed tungsten acetylene complexes and investigated their reactivity. Here, we report the first intermolecular nucleophilic attack on a tungsten-bound acetylene (C(2)H(2)) in bioins...

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Bibliografiske detaljer
Udgivet i:Inorg Chem
Main Authors: Ehweiner, Madeleine A., Peschel, Lydia M., Stix, Niklas, Ćorović, Miljan Z., Belaj, Ferdinand, Mösch-Zanetti, Nadia C.
Format: Artigo
Sprog:Inglês
Udgivet: American Chemical Society 2021
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC8220502/
https://ncbi.nlm.nih.gov/pubmed/33852290
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.1c00643
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