Copper‐Catalyzed Asymmetric Silylation of Propargyl Dichlorides: Access to Enantioenriched Functionalized Allenylsilanes

A copper‐catalyzed silylation of propargyl dichlorides was developed to access chloro‐substituted allenylsilanes under mild reaction conditions. Moreover, enantioenriched chloro‐substituted allenylsilanes can be synthesized in moderate to high yields and good enantioselectivities with this protocol....

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Liu, Zheng‐Li, Yang, Chao, Xue, Qi‐Yan, Zhao, Meng, Shan, Cui‐Cui, Xu, Yun‐He, Loh, Teck‐Peng
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2019
Fag:
Communications
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6899605/
https://ncbi.nlm.nih.gov/pubmed/31532868
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201908343
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