Copper‐Catalyzed Asymmetric Silylation of Propargyl Dichlorides: Access to Enantioenriched Functionalized Allenylsilanes

A copper‐catalyzed silylation of propargyl dichlorides was developed to access chloro‐substituted allenylsilanes under mild reaction conditions. Moreover, enantioenriched chloro‐substituted allenylsilanes can be synthesized in moderate to high yields and good enantioselectivities with this protocol....

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Detalles Bibliográficos
Publicado en:Angew Chem Int Ed Engl
Main Authors: Liu, Zheng‐Li, Yang, Chao, Xue, Qi‐Yan, Zhao, Meng, Shan, Cui‐Cui, Xu, Yun‐He, Loh, Teck‐Peng
Formato: Artigo
Idioma:Inglês
Publicado: John Wiley and Sons Inc. 2019
Assuntos:
Communications
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6899605/
https://ncbi.nlm.nih.gov/pubmed/31532868
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201908343
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