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Stereocontrol in Palladium-Catalyzed Propargylic Substitutions: Kinetic Resolution to give Enantioenriched 1,5-Enynes and Propargyl Acetates

Kinetic resolution during the catalytic allyl-propargyl cross-coupling with chiral starting materials can be accomplished with a chiral Palladium catalyst. These reactions offer ready access to enantiomerically enriched enyne products from simple readily available starting materials.

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: Ardolino, Michael J., Eno, Meredith S., Morken, James P.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2013
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC4019443/
https://ncbi.nlm.nih.gov/pubmed/24839434
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201300720
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