Light‐Induced Mechanistic Divergence in Gold(I) Catalysis: Revisiting the Reactivity of Diazonium Salts

In a systematic study of the Au‐catalyzed reaction of o‐alkynylphenols with aryldiazonium salts, we find that essentially the same reaction conditions lead to a change in mechanism when a light source is applied. If the reaction is carried out at room temperature using a Au(I) catalyst, the diazoniu...

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Publicado en:Angew Chem Int Ed Engl
Autores principales: Taschinski, Svenja, Döpp, René, Ackermann, Martin, Rominger, Frank, de Vries, Folkert, Menger, Maximilian F. S. J., Rudolph, Matthias, Hashmi, A. Stephen K., Klein, Johannes E. M. N.
Formato: Artigo
Lenguaje:Inglês
Publicado: John Wiley and Sons Inc. 2019
Materias:
Research Articles
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC6899485/
https://ncbi.nlm.nih.gov/pubmed/31552696
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201908268
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