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Dual gold/photoredox-catalyzed C(sp)–H arylation of terminal alkynes with diazonium salts

The arylation of alkyl and aromatic terminal alkynes by a dual gold/photoredox catalytic system is described. Using aryldiazonium salts as readily available aryl sources, a range of diversely-functionalized arylalkynes could be synthesized under mild, base-free reaction conditions using visible ligh...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Tlahuext-Aca, Adrian, Hopkinson, Matthew N., Sahoo, Basudev, Glorius, Frank
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5950757/
https://ncbi.nlm.nih.gov/pubmed/29861968
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02583d
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