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Cyclopropanation of Benzene Rings by Oxidatively Generated α-Oxo Gold Carbene: One-Pot Access to Tetrahydropyranone-Fused Cycloheptatrienes from Propargyl Benzyl Ethers

Cyclopropanations of benzene rings by oxidatively generated α-oxo gold carbenes are for the first time demonstrated in a Buchner reaction, in which readily available propargyl benzyl ethers are converted in one-pot to tetrahydropyranone-fused cycloheptatrienes via sequential oxidative gold catalysis...

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Bibliographic Details
Published in:Adv Synth Catal
Main Authors: Ji, Kegong, Zhang, Liming
Format: Artigo
Language:Inglês
Published: 2017
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6897493/
https://ncbi.nlm.nih.gov/pubmed/31814809
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201701322
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