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Optimizing P,N-Bidentate Ligands for Oxidative Gold Catalysis: Highly Efficient Intermolecular Trapping of α-Oxo Gold Carbenes by Carboxylic Acids
Steric Bulk or Conformation Control? Optimization of P,N-bidentate ligands reveals the importance of conformation control in the development of highly efficient intermolecular trapping of reactive α-oxo gold carbene intermediates. While a pendant piperidine ring offers suitable steric bulk, fixing i...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3718277/ https://ncbi.nlm.nih.gov/pubmed/23640818 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201301601 |
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