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Dialkylation of Indoles with Trichloroacetimidates to Access 3,3-Disubstituted Indolenines

2-Substituted indoles may be directly transformed to 3,3-dialkyl indolenines with trichloroacetimidate electrophiles and the Lewis acid TMSOTf. These reactions provide rapid access to complex indolenines which are present in a variety of complex natural products and medicinally relevant small molecu...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Suzuki, Tamie, Mate, Nilamber A., Adhikari, Arijit A., Chisholm, John D.
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6891773/
https://ncbi.nlm.nih.gov/pubmed/31731742
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules24224143
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