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Total Synthesis of Hinduchelins A–D, Stereochemical Revision of Hinduchelin A, and Biological Evaluation of Natural and Unnatural Analogues

Here, we report the first total synthesis of hinduchelins A–D, a family of nontoxic catechol derivatives from Streptoalloteichus hindustanus, possessing a druglike chemotype and modest iron-chelating ability. A concise synthesis was developed employing methyl 5-methyloxazole-4-carboxylate as a singl...

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Detalhes bibliográficos
Publicado no:J Org Chem
Main Authors: Childress, Elizabeth S., Garrison, Aaron T., Sheldon, Jessica R., Skaar, Eric P., Lindsley, Craig W.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6863084/
https://ncbi.nlm.nih.gov/pubmed/31039303
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.9b00391
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