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A Highly Chemo-, Regio-, and Stereoselective Metallacycle-Mediated Annulation Between a Conjugated Enyne and an Ene-Diyne

Alkoxide-directed metal-centered intermolecular [2+2+2] annulation is shown to chemo-, regio-, and stereoselectively engage two polyunsaturated substrate in productive cyclization chemistry. This annulation process is unique in the field, revealing that it is possible to selectively engage three of...

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Publicat a:ARKIVOC
Autors principals: Shalit, Zachary A., Micalizio, Glenn C.
Format: Artigo
Idioma:Inglês
Publicat: 2018
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6860972/
https://ncbi.nlm.nih.gov/pubmed/31742254
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.24820/ark.5550190.p010.487
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