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Template catalysis by manganese pincer complexes: oxa- and aza-Michael additions to unsaturated nitriles

Activation of C[triple bond, length as m-dash]N bonds by metal–ligand cooperation provides a new route for the functionalization of nitriles. Herein, we report the electrophilic activation of unsaturated nitriles by dearomatized manganese pincer complexes for the oxa- and aza-Michael addition reacti...

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Détails bibliographiques
Publié dans:Chem Sci
Auteurs principaux: Tang, Shan, Milstein, David
Format: Artigo
Langue:Inglês
Publié: Royal Society of Chemistry 2019
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6855260/
https://ncbi.nlm.nih.gov/pubmed/31762979
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03269j
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