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Merging Regiodivergent Catalysis with Atom‐Economical Radical Arylation

A titanocene‐catalyzed regiodivergent radical arylation is described that allows access to either enantiomerically pure tetrahydroquinolines or indolines from a common starting material. The regioselectivity of epoxide opening that results in the high selectivity of heterocycle formation is controll...

Deskribapen osoa

Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Angew Chem Int Ed Engl
Egile Nagusiak: Mühlhaus, Felix, Weißbarth, Hendrik, Dahmen, Tobias, Schnakenburg, Gregor, Gansäuer, Andreas
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: John Wiley and Sons Inc. 2019
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC6852184/
https://ncbi.nlm.nih.gov/pubmed/31394024
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201908860
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