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Merging Regiodivergent Catalysis with Atom‐Economical Radical Arylation
A titanocene‐catalyzed regiodivergent radical arylation is described that allows access to either enantiomerically pure tetrahydroquinolines or indolines from a common starting material. The regioselectivity of epoxide opening that results in the high selectivity of heterocycle formation is controll...
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Udgivet i: | Angew Chem Int Ed Engl |
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Main Authors: | , , , , |
Format: | Artigo |
Sprog: | Inglês |
Udgivet: |
John Wiley and Sons Inc.
2019
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Fag: | |
Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6852184/ https://ncbi.nlm.nih.gov/pubmed/31394024 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201908860 |
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