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Transforming Olefins into γ,δ-Unsaturated Nitriles by Cu-Catalysis
We developed a strategy to transform olefins into homoallylic nitriles by a mechanism that combines copper catalysis with alkyl nitrile radicals. The radicals are easily generated from alkyl nitriles in the presence of a mild oxidant, di-terf-butyl peroxide. This cross-dehydrogenative coupling betwe...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2017
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6824592/ https://ncbi.nlm.nih.gov/pubmed/28796438 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201705859 |
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