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Substance P in solution: trans-to-cis configurational changes of penultimate prolines initiate non-enzymatic peptide bond cleavages
We report ion mobility spectrometry and mass spectrometry studies of the non-enzymatic step-by-step degradation of substance P (subP), an eleven-residue neuropeptide, with the sequence Arg(1)-Pro(2)-Lys(3)-Pro(4)-Gln(5)-Gln(6)-Phe(7)-Phe(8)-Gly(9)-Leu(10)-Met(11)-NH(2), in ethanol. At elevated solut...
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| Publicado no: | J Am Soc Mass Spectrom |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6824264/ https://ncbi.nlm.nih.gov/pubmed/30980380 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s13361-019-02159-w |
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