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Unexpected Formation of Hexasubstituted Arenes through a Twofold Palladium-Mediated Ligand Arylation
A rearrangement reaction of biarylphosphine-supported Pd(II) complexes was employed to synthesize 1,3,5-triaryl 2,4,6-triisopropylbenzene compounds, a class of molecules that has not previously been reported. The strain of the central hexasubstituted ring was investigated via X-ray crystallography.
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| Udgivet i: | J Org Chem |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2019
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6822615/ https://ncbi.nlm.nih.gov/pubmed/31512875 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.9b02091 |
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