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Design of New Ligands for the Palladium-Catalyzed Arylation of α-Branched Secondary Amines

In Pd-catalyzed C–N cross-coupling reactions, α-branched secondary amines are difficult coupling partners and the desired products are often produced in low yields. To provide a robust method for accessing N-aryl α-branched tertiary amines, new catalysts have been designed to suppress undesired side...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Park, Nathaniel H., Vinogradova, Ekaterina V., Surry, David S., Buchwald, Stephen L.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4490068/
https://ncbi.nlm.nih.gov/pubmed/26032920
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201502626
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