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Tetrahedral Iron Featuring an Appended Lewis Acid: Distinct Pathways for the Reduction of Hydroxylamine and Hydrazine

We present the preparation of a nitrogen-based bidentate ligand featuring an appended boron Lewis acid as well as its tetrahedral Fe(2+) and Zn(2+) complexes. These complexes act as platforms for hydrazine and hydroxylamine capture and reduction chemistry.

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Pubblicato in:Chem Commun (Camb)
Autori principali: Kiernicki, John J., Norwine, Emily E., Zeller, Matthias, Szymczak, Nathaniel K.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2019
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6776999/
https://ncbi.nlm.nih.gov/pubmed/31528878
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9cc05720j
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