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Hydrazine Capture and N–N Bond Cleavage at Iron Enabled by Flexible Appended Lewis Acids
Incorporation of two 9-borabicyclo[3.3.1]-nonyl substituents within the secondary coordination sphere of a pincer-based Fe(II) complex provides Lewis acidic sites capable of binding 1 or 2 equiv of N(2)H(4). Reduction of the 1:1 Fe:N(2)H(4) species affords a rare Fe(NH(2))(2) complex in which the am...
में बचाया:
| में प्रकाशित: | J Am Chem Soc |
|---|---|
| मुख्य लेखकों: | , , |
| स्वरूप: | Artigo |
| भाषा: | Inglês |
| प्रकाशित: |
2017
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| विषय: | |
| ऑनलाइन पहुंच: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5955611/ https://ncbi.nlm.nih.gov/pubmed/29227655 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b11465 |
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