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Hydrazine Capture and N–N Bond Cleavage at Iron Enabled by Flexible Appended Lewis Acids

Incorporation of two 9-borabicyclo[3.3.1]-nonyl substituents within the secondary coordination sphere of a pincer-based Fe(II) complex provides Lewis acidic sites capable of binding 1 or 2 equiv of N(2)H(4). Reduction of the 1:1 Fe:N(2)H(4) species affords a rare Fe(NH(2))(2) complex in which the am...

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Bibliografiske detaljer
Udgivet i:J Am Chem Soc
Main Authors: Kiernicki, John J., Zeller, Matthias, Szymczak, Nathaniel K.
Format: Artigo
Sprog:Inglês
Udgivet: 2017
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5955611/
https://ncbi.nlm.nih.gov/pubmed/29227655
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b11465
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