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Mobility of Lewis Acids within the Secondary Coordination Sphere: Toward a Model for Cooperative Substrate Binding
Distance dependence of appended Lewis acids in N(2)H(4) binding and deprotonation was evaluated within a series of zinc complexes. Variation of spacer-length to a tethered trialkylborane Lewis acid revealed distinct preferences for binding and stabilization of the resulting deprotonated N(2)H(3)(−)...
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| Publicado no: | Chem Commun (Camb) |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7606458/ https://ncbi.nlm.nih.gov/pubmed/33016291 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0cc05121g |
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