Site‐Selective, Remote sp(3) C−H Carboxylation Enabled by the Merger of Photoredox and Nickel Catalysis

A photoinduced carboxylation of alkyl halides with CO(2) at remote sp(3) C−H sites enabled by the merger of photoredox and Ni catalysis is described. This protocol features a predictable reactivity and site selectivity that can be modulated by the ligand backbone. Preliminary studies reinforce a rat...

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Bibliographische Detailangaben
Veröffentlicht in:Chemistry
Hauptverfasser: Sahoo, Basudev, Bellotti, Peter, Juliá‐Hernández, Francisco, Meng, Qing‐Yuan, Crespi, Stefano, König, Burkhard, Martin, Ruben
Format: Artigo
Sprache:Inglês
Veröffentlicht: John Wiley and Sons Inc. 2019
Schlagworte:
Communications
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6773098/
https://ncbi.nlm.nih.gov/pubmed/31074058
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201902095
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