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Deoxygenative Borylation of Secondary and Tertiary Alcohols

Two different approaches for the deoxygenative radical borylation of secondary and tertiary alcohols are presented. These transformations either proceed through a metal‐free silyl‐radical‐mediated pathway or utilize visible‐light photoredox catalysis. Readily available xanthates or methyl oxalates a...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Friese, Florian W., Studer, Armido
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2019
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6772128/
https://ncbi.nlm.nih.gov/pubmed/31050141
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201904028
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