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Hydrogen Bond Directed ortho‐Selective C−H Borylation of Secondary Aromatic Amides

Reported is an iridium catalyst for ortho‐selective C−H borylation of challenging secondary aromatic amide substrates, and the regioselectivity is controlled by hydrogen‐bond interactions. The BAIPy‐Ir catalyst forms three hydrogen bonds with the substrate during the crucial activation step, and all...

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Detaylı Bibliyografya
Yayımlandı:Angew Chem Int Ed Engl
Asıl Yazarlar: Bai, Shao‐Tao, Bheeter, Charles B., Reek, Joost N. H.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: John Wiley and Sons Inc. 2019
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC6772079/
https://ncbi.nlm.nih.gov/pubmed/31237988
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201907366
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