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Hydrogen Bond Directed ortho‐Selective C−H Borylation of Secondary Aromatic Amides
Reported is an iridium catalyst for ortho‐selective C−H borylation of challenging secondary aromatic amide substrates, and the regioselectivity is controlled by hydrogen‐bond interactions. The BAIPy‐Ir catalyst forms three hydrogen bonds with the substrate during the crucial activation step, and all...
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| Pubblicato in: | Angew Chem Int Ed Engl |
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| Autori principali: | , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
John Wiley and Sons Inc.
2019
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6772079/ https://ncbi.nlm.nih.gov/pubmed/31237988 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201907366 |
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