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α‐Arylation of Carbonyl Compounds through Oxidative C−C Bond Activation

A synthetically useful approach for the direct α‐arylation of carbonyl compounds through a novel oxidative C−C bond activation is reported. This mechanistically unusual process relies on a 1,2‐aryl shift and results in all‐carbon quaternary centers. The transformation displays broad functional‐group...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Li, Jing, Bauer, Adriano, Di Mauro, Giovanni, Maulide, Nuno
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2019
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6771532/
https://ncbi.nlm.nih.gov/pubmed/31112360
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201904899
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