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A Catalytic Cross‐Olefination of Diazo Compounds with Sulfoxonium Ylides
A ruthenium‐catalysed cross‐olefination of diazo compounds and sulfoxonium ylides is presented. Our reaction design exploits the intrinsic difference in reactivity of diazo compounds and sulfoxonium ylides as both carbene precursors and nucleophiles, which results in a highly selective reaction.
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| 出版年: | Angew Chem Int Ed Engl |
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| 主要な著者: | , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
John Wiley and Sons Inc.
2018
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6283242/ https://ncbi.nlm.nih.gov/pubmed/30264529 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201809934 |
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