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A Catalytic Cross‐Olefination of Diazo Compounds with Sulfoxonium Ylides

A ruthenium‐catalysed cross‐olefination of diazo compounds and sulfoxonium ylides is presented. Our reaction design exploits the intrinsic difference in reactivity of diazo compounds and sulfoxonium ylides as both carbene precursors and nucleophiles, which results in a highly selective reaction.

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書誌詳細
出版年:Angew Chem Int Ed Engl
主要な著者: Neuhaus, James D., Bauer, Adriano, Pinto, Alexandre, Maulide, Nuno
フォーマット: Artigo
言語:Inglês
出版事項: John Wiley and Sons Inc. 2018
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC6283242/
https://ncbi.nlm.nih.gov/pubmed/30264529
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201809934
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