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A Catalytic Cross‐Olefination of Diazo Compounds with Sulfoxonium Ylides
A ruthenium‐catalysed cross‐olefination of diazo compounds and sulfoxonium ylides is presented. Our reaction design exploits the intrinsic difference in reactivity of diazo compounds and sulfoxonium ylides as both carbene precursors and nucleophiles, which results in a highly selective reaction.
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6283242/ https://ncbi.nlm.nih.gov/pubmed/30264529 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201809934 |
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