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Enantioselective Radical Addition/Cross-Coupling of Organozinc Reagents, Alkyl Iodides, and Alkenylboron Reagents

A hybrid transition metal/radical process is described that results in the addition of organozinc reagents and alkyl halides across alkenylboron reagents in an enantioselective catalytic fashion. The reaction can be accomplished both intermolecularly and intramolecularly, providing useful product yi...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Chierchia, Matteo, Xu, Peilin, Lovinger, Gabriel J., Morken, James P.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2019
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6764867/
https://ncbi.nlm.nih.gov/pubmed/31390474
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201908029
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