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Ni-Catalyzed Enantioselective Conjunctive Coupling with C(sp(3)) Electrophiles: A Radical-Ionic Mechanistic Dichotomy

The catalytic enantioselective conjunctive coupling of C(sp(3)) electrophiles can be accomplished with Ni catalysis. The enantioselectivity of the reaction is dependent on reaction mechanism with many substrates able to engage in an asymmetric process with Pybox-Ni complexes, whereas other substrate...

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Xehetasun bibliografikoak
Argitaratua izan da:J Am Chem Soc
Egile Nagusiak: Lovinger, Gabriel J., Morken, James P.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2017
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC6598435/
https://ncbi.nlm.nih.gov/pubmed/29116784
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b10519
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