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Ni-Catalyzed Enantioselective Conjunctive Coupling with C(sp(3)) Electrophiles: A Radical-Ionic Mechanistic Dichotomy
The catalytic enantioselective conjunctive coupling of C(sp(3)) electrophiles can be accomplished with Ni catalysis. The enantioselectivity of the reaction is dependent on reaction mechanism with many substrates able to engage in an asymmetric process with Pybox-Ni complexes, whereas other substrate...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6598435/ https://ncbi.nlm.nih.gov/pubmed/29116784 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b10519 |
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