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Ni-Catalyzed Enantioselective Conjunctive Coupling with C(sp(3)) Electrophiles: A Radical-Ionic Mechanistic Dichotomy
The catalytic enantioselective conjunctive coupling of C(sp(3)) electrophiles can be accomplished with Ni catalysis. The enantioselectivity of the reaction is dependent on reaction mechanism with many substrates able to engage in an asymmetric process with Pybox-Ni complexes, whereas other substrate...
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| 出版年: | J Am Chem Soc |
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| 主要な著者: | , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2017
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6598435/ https://ncbi.nlm.nih.gov/pubmed/29116784 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b10519 |
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